Here is the full list of all 47 Rocksmith 2014 achievements.
Attempt and fail Score Attack 10 times in a row
Clear 50 songs on Score Attack Easy, Medium, Hard or Master
Hit all bass techniques at least once
Play all Rocksmith 2014 songs at least once
Clear 30 songs on Score Attack Medium, Hard or Master
Complete all 6 levels in a Scale Set in Scale Warriors
Complete 60 minutes in Session Mode
Clear 15 songs on Score Attack Master
Clear 20 songs on Score Attack Hard or Master
Achieve 100% Mastery on 10 songs
Successfully play 30 unique chords
Play with over 50 instruments
Complete 214 Missions
Score 10,000,000 points in String Skip Saloon
Score 10,000,000 points in Temple of Bends
Play Session Mode between 11:59pm and 3am
Score at least 10,000,000 points in Hurtlin' Hurdles
Create and save a tone using Eden gear
Play Learn a Song for 25 hours
Complete 50 RS Recommends items
Hit all guitar techniques at least once
Play Learn a Song for 10 hours
Play Rocksmith 2014 on 5 consecutive days
Get Platinum on Score Attack Easy, Medium, Hard or Master
Get Platinum on Score Attack Medium, Hard or Master
Get Platinum on Score Attack Hard or Master
Get Platinum on Score Attack Master
Score at least 10,000,000 points in Gone Wailin’
Score at least 10,000,000 points in Star Chords
Score 10,000,000 points in Scale Racer
Score at least 10,000,000 points in Ducks ReDux
Use the One More Song feature
Exclude a song from the Nonstop Play playlist
Score 10,000,000 points in Harmonic Heist
Get a streak over 250 that bridges multiple songs
Score at least 10,000,000 points in Ninja Slide N
Complete 4 Session Mode Missions
Complete all 3 levels in a Progression in Return to Castle Chordead
Clear 1 song on Score Attack Master
Keep the band alive for over 12 minutes in Session Mode
Create and save a tone using Orange gear
Play Session Mode between 10am and 2pm
Create and save a tone using Marshall gear
Achieve 100% Mastery on any song
Play a Solo at >95% Accuracy
Complete Soundcheck
Complete 500 Missions