Full list of all 38 Rise of Nations: Extended Edition achievements. It takes around 60-80 hours to unlock all of the achievements on Windows.
Destroy 10,000 buildings
Build 10,000 buildings
Train 10,000 air units
Train 50,000 artillery units
Train 1,000,000 infantry units
Kill 50,000 units
Lose 100,000 units
Train 1,000,000 cavalry units
Train 25,000 naval units
Finish a multiplayer game
Beat Tougher
Beat Toughest
Finish a game in Armageddon
Get a high score on any skill
Research 4 finals in game
Win Wonder
Win Musical Chairs
Knockout in Sudden Death
Win Peaceful Tech Race
Win Assassin
Complete the World Map Campaign
Win 100 games
Complete Espionage as the Soviets
Complete Espionage as the USA
Complete the Cold War Campaign
Complete the New World Campaign
Gain control of 250 rare resources
Complete the Napoleon Campaign
Win 50 games
Complete the Alexander the Great Campaign
Collect 5,000 resources from ruins
Win 25 games
Collect 1,000,000 resources
Win 10 games
Win on a Big Huge Map
Send resources to an ally
Win Territory
Capture a city