Here is the full list of all 25 PokerStars VR achievements.
Win Two Hands Consecutively
Win Your First Hand
Bust 100 Players
Bet 1 Million In Games
Win 10 Spin N' Go Tournaments
Spin The Wheel 100 Times
Win Your First Spin N' Go Tournament
Play Your First Spin N' Go Tournament
Win a Million Chips In Games
Bust A Player
Play A Thousand Hands
Play 100 Hands
Win Your First Thousand Chips
Play Your First Hand
Play 100000 Hands
Win 100000 Hands
Raise A Total Of A Million Chips
Win 200 Tournaments (Sit N' Go or Spin N' Go)
Win Your First Sit N' Go Tournament
Play Your First Sit N' Go Tournament
Win A Hand With A Royal Flush
Win A Hand With A Straight Flush
Win A Thousand Hands
Win 10 Sit N' Go Tournaments
Win 100 Hands