Here is the full list of all 25 PokerStars VR achievements.
Win Your First Hand
Raise A Total Of A Million Chips
Bust 100 Players
Spin The Wheel 100 Times
Play A Thousand Hands
Bet 1 Million In Games
Win a Million Chips In Games
Play Your First Spin N' Go Tournament
Play 100 Hands
Bust A Player
Win Your First Thousand Chips
Play Your First Hand
Play 100000 Hands
Win 100000 Hands
Win 200 Tournaments (Sit N' Go or Spin N' Go)
Win Your First Sit N' Go Tournament
Play Your First Sit N' Go Tournament
Win Your First Spin N' Go Tournament
Win A Hand With A Royal Flush
Win Two Hands Consecutively
Win A Hand With A Straight Flush
Win A Thousand Hands
Win 10 Spin N' Go Tournaments
Win 10 Sit N' Go Tournaments
Win 100 Hands