Here is the full list of all 25 PokerStars VR achievements.
Play A Thousand Hands
Spin The Wheel 100 Times
Win 10 Spin N' Go Tournaments
Win Your First Spin N' Go Tournament
Play Your First Spin N' Go Tournament
Bust A Player
Play 100 Hands
Win Your First Thousand Chips
Play Your First Hand
Win Your First Hand
Play 100000 Hands
Win 100000 Hands
Bet 1 Million In Games
Raise A Total Of A Million Chips
Bust 100 Players
Win 200 Tournaments (Sit N' Go or Spin N' Go)
Win a Million Chips In Games
Win Your First Sit N' Go Tournament
Play Your First Sit N' Go Tournament
Win A Hand With A Royal Flush
Win Two Hands Consecutively
Win A Hand With A Straight Flush
Win A Thousand Hands
Win 10 Sit N' Go Tournaments
Win 100 Hands