Here is the full list of all 25 PokerStars VR achievements.
Win 100 Hands
Play 100 Hands
Bust A Player
Win Two Hands Consecutively
Win Your First Hand
Win Your First Thousand Chips
Play Your First Hand
Play 100000 Hands
Win 100000 Hands
Bet 1 Million In Games
Raise A Total Of A Million Chips
Bust 100 Players
Win 200 Tournaments (Sit N' Go or Spin N' Go)
Win a Million Chips In Games
Win Your First Sit N' Go Tournament
Play Your First Sit N' Go Tournament
Play Your First Spin N' Go Tournament
Win Your First Spin N' Go Tournament
Win A Hand With A Royal Flush
Win A Hand With A Straight Flush
Play A Thousand Hands
Win A Thousand Hands
Spin The Wheel 100 Times
Win 10 Spin N' Go Tournaments
Win 10 Sit N' Go Tournaments