Here is the full list of all 21 Plants vs. Zombies GOTY Edition achievements. It takes around 40-50 hours to unlock all of the achievements on Windows.
Grow the Tree of Wisdom to 100 feet
Discover the top secret zombie
Hypnotize the lead dancer zombie
Collect all 49 plants
Get to 20 flags in Survival Endless
Defeat 2 Gargantuars with Corn Cob missiles in a single level.
Get the golden sunflower trophy
Beat all 20 mini games.
Complete a daytime level by planting only Mushrooms and Coffee Beans.
Bowl over 5 zombies with a single Wall-Nut.
Enable Mustache Mode
Get to a streak of 10 in I, Zombie Endless
Get to a streak of 15 in Vasebreaker Endless
Get 8000 sun during a single level.
Complete adventure mode
Defeat a normal roof level without using any catapult plants.
Pick up 30 coins in a row on a single level without letting any disappear.
Blow up 10 zombies with a single cherry bomb
Complete a daytime pool level without using pea shooters of any kind.
Complete a nighttime level without planting any Mushrooms.
Blow up a zombie using a potato mine