Here is the full list of all 50 Pixel Puzzles Junior achievements. It takes around 0-1 hour to unlock all of the achievements on Windows.
Complete Puzzle Ladybugs
Complete Puzzle Frog
Complete Puzzle Colors
Complete Puzzle Snowman
Complete Puzzle Lion
Complete Puzzle Rainbow
Complete Puzzle Dragon
Complete Puzzle Beach
Complete Puzzle Octopus
Complete Puzzle Mirror
Complete Puzzle Kangaroo
Complete Puzzle Boat
Complete Puzzle Reindeer
Complete Puzzle Western
Complete Puzzle Egg
Complete Puzzle Cave
Complete Puzzle Blobs
Complete Puzzle Flower
Complete Puzzle Wrestler
Complete Puzzle Monster
Complete Puzzle Fish
Complete Puzzle Blur
Complete Puzzle Whale
Complete Puzzle Sunny
Complete Puzzle Smile
Complete Puzzle Veggies
Complete Puzzle Cows
Complete Puzzle Girl
Complete Puzzle Wolf
Complete Puzzle Turtle
Complete Puzzle Bunny
Complete Puzzle Cake
Complete Puzzle Dino
Complete Puzzle Roach
Complete Puzzle Broom
Complete Puzzle Owl
Complete Puzzle Sealion
Complete Puzzle Castle
Complete Puzzle Sun
Complete Puzzle Hiss
Complete Puzzle Birds
Complete Puzzle Jester
Complete Puzzle Fire
Complete Puzzle Snake
Complete Puzzle Night
Complete Puzzle Cavemen
Complete Puzzle Racoon
Complete Puzzle Witch
Complete Puzzle Alien
Complete Puzzle Elephants