Here is the full list of all 27 Orcs Must Die! 2 achievements. It takes around 40-50 hours to unlock all of the achievements on Windows.
Kill 50,000 Orcs
Kill 1,000 orcs with minecarts
Spend 1000 skulls in the tome
Complete all classic levels
Use the berserker trinket to reduce your health below 15%
Beat a nightmare level using only weapons, trinkets, and the dwarf, archer, and paladin minions
Complete campaign, Act 2 Nightmare
Kill 25,000 Orcs
Collect 30 dropped skulls
Complete campaign, Act 1 Nightmare
Get a 25 kill streak
Complete campaign, Act 2
Complete Twisted Halls in co-op
Earn 5 (base) skulls on every campaign level on War Mage difficulty
Use the freedom trinket to break a co-op partner out of a stun
Heal an ally in co-op
Reach wave 50 in an endless mode level
Reach wave 25 in an endless mode level
Reach wave 40 in a co-op endless mode level
Catch the Robot disease
Get a 10x or higher combo
Spend 100 skulls in the tome
Complete campaign, Act 1
Charm 100 orcs as the Sorceress
Respec your character
Spend 10 skulls in the tome
Get a 10 kill streak