Here is the full list of all 27 Orcs Must Die! 2 achievements. It takes around 40-50 hours to unlock all of the achievements on Windows.
Collect 30 dropped skulls
Reach wave 40 in a co-op endless mode level
Kill 25,000 Orcs
Use the freedom trinket to break a co-op partner out of a stun
Use the berserker trinket to reduce your health below 15%
Beat a nightmare level using only weapons, trinkets, and the dwarf, archer, and paladin minions
Complete all classic levels
Catch the Robot disease
Charm 100 orcs as the Sorceress
Reach wave 25 in an endless mode level
Get a 25 kill streak
Complete Twisted Halls in co-op
Complete campaign, Act 2
Spend 100 skulls in the tome
Complete campaign, Act 1
Heal an ally in co-op
Spend 10 skulls in the tome
Respec your character
Get a 10 kill streak
Kill 50,000 Orcs
Complete campaign, Act 1 Nightmare
Complete campaign, Act 2 Nightmare
Reach wave 50 in an endless mode level
Earn 5 (base) skulls on every campaign level on War Mage difficulty
Spend 1000 skulls in the tome
Get a 10x or higher combo
Kill 1,000 orcs with minecarts