Here is the full list of all 12 Orbital Gear achievements.
Kill 500 Gears
Knock an opponent out of the stage
Shoot down 10 projectiles
Get the most assists in a match
Kill the same player three times in a row
Kill two Gears without landing
Get the most kills in a match
Destroy 100 buildings in Orbital Warfare
Kill 10 Gears with Mines
Stop 50 projectiles with shields
Hit two players with the same Discharger shot
Hit two players with the same Gauntlet attack