Here is the full list of all 19 Orangeblood achievements.
Clear the campaign.
Takeover the Sunrise Hotel.
Clear Tier 3.
Receive a present from the dog.
Takeover the China Lake Restaurant.
Clear Tier 2.
Takeover the Smile Bakery.
Clear Tier 1.
Defeat Box Dog.
Retake Club Shangri-La.
Reach the Dump Site.
Deal 1,000,000 in one hit.
Defeat Doggopter.
Defeat Armored Barricade.
Defeat Chef.
Defeat Homerun Sempai, and sit on the throne.
Defeat Evil Chef.
Defeat Green Yakuza.
Defeat Vice Admiral after clearing out all the safes.