Here is the full list of all 20 Old School RuneScape achievements. It takes around 0-1 hour to unlock all of the achievements on Windows.
Complete a Clue Scroll
Ride the canoe in Lumbridge
Visit the General Stores in Lumbridge, Falador, Varrock, Edgeville, Rimmington, Al-kharid and Karamja (Musa point)
Enter the Wilderness
Chat clothing with Thessalia in Varrock
Catch a Tuna at Musa Point
Complete the Dragon Slayer quest
Pass through the Al-Kharid/Lumbridge gate without paying
Vote in a Poll or view Poll results
Craft some Air Runes at the Air Altar
Complete the Vampyre Slayer quest
Equip a Mithril Scimitar
Complete the Demon Slayer Quest
Equip Fancy Boots or Fighting Boots from Stronghold of Security
Visit Death's Domain
Reach Combat level 20
Reach a total level of 100
Complete the Cook's Assistant quest
Complete the Tutorial
Use the Home Teleport Spell with any spellbook