Here is the full list of all 50 Naruto Shippuden: Ultimate Ninja Storm Revolution achievements.
Achieve Rank S in all 5 battles in "Creation of the Akatsuki".
Acquired an Ultimate Jutsu Orb.
Acquired an Awakening Orb.
Finished a job for the first time.
C Rank Beginner Tournament cleared.
B Rank Intermediate Tournament cleared.
A Rank Advanced Tournament cleared.
S Rank Special Tournament cleared.
S+ Rank Ultimate Tournament cleared.
Cleared the Mecha-Naruto story.
Cleared all D Rank Challenges.
Cleared all C Rank Challenges.
Cleared all B Rank Challenges.
Cleared all A Rank Challenges.
Cleared all S Rank Challenges.
Successfully used a Counterattack.
Hit a Guard Break attack.
Landed a Combo Ultimate Jutsu.
Won a battle without taking a single hit.
Hit a Seal Barrier.
Finished the opponent off using True Awakening.
Finished the opponent off using Support Drive 2.
Used a discount coupon.
Used a medal.
Customized a character.
Defeated 30 opponents in Ultimate Survival.
Cleared all Beginner Ability Cap Survival challenges.
Cleared all Intermediate Ability Cap Survival challenges.
Cleared all Advanced Ability Cap Survival challenges.
Won a tournament for the first time.
Won an Ever-Changing Tournament for the first time.
Won a Free Battle League for the first time.
Won the Ever-Changing League for the first time.
Cleared out Beginner Challenge League.
Cleared out Intermediate Challenge League.
Cleared out Advanced Challenge League.
Acquired all Achievements.
Activated a rail action.
Did a 50 combo attack.
"The Far Reaches of Hope" cleared.
"The Two Uchiha" cleared.
Achieve Rank S in both battles in "The Two Uchiha".
D Rank Entry Tournament cleared.
Caused a Team Bonus in a 4-person battle.
Forced an opponent out of a 4-Person Battle.
Cleared an Ally Event for the first time.
Used a lottery ticket.
"Creation of the Akatsuki" cleared.
Finished the opponent off with a Team Ultimate Jutsu.
Did an Ultimate Finish.