Here is the full list of all 28 MultiVersus achievements.
Win 10 matchmade games
Get 10 Ringouts using the right-side of the Blast Zone
Give out 5 Toasts to other players
Play 1 matchmade game
Give out 10 Toasts to other players
Give out 100 Toasts to other players
Accept 100 rematches
Get 30 Ringouts
Get 50 Ringouts
Get 100 Ringouts
Win 100 matchmade games
Win 300 matchmade games
Get 10 Double Ringouts
Get 25 Double Ringouts
Get 100 Double Ringouts
Get 10 Ringouts using your spike
Get 50 Ringouts using your spike
Get 100 Ringouts using your spike
Get 10 Ringouts using the top of the Blast Zone
Get 10 Ringouts using the left-side of the Blast Zone
Get 10 Ringouts using the bottom of the Blast Zone
Get 20 Ringouts with a Projectile
Get 50 Ringouts with a Projectile
Get 200 Ringouts with a Projectile
Play 25 matches in a party
Play 100 matches in a party
Play 500 matches in a party
Get 10 low-damage Ringouts