Here is the full list of all 33 Mitsurugi Kamui Hikae achievements. It takes around 8-10 hours to unlock all of the achievements on Windows.
Defeat stage 3 boss "Suzuka" (any difficulty)
Defeat stage 4 boss "Magatsu Kaina" (any difficulty)
Use Zanshin to defeat 50 enemies
Use Zanshin to defeat 100 enemies
Perform 10 Just Guards
Perform a Counter
Perform a Flourish
Defeat stage 2 boss "Kaiser" (any difficulty)
Complete all upgrades
Collect 100,000 SP
Max out Life Gauge
Max out Katana Gauge
Watch the tutorial
Defeat 100 enemies
Perform the holy technique "Divine Wind"
Perform a Just Guard
Defeat stage 1 boss "Kaina" (any difficulty)
Defeat 10 enemies
Use Zanshin to defeat an enemy
String 50 hits
String 100 hits
Perform the holy technique "Celestial Judgement"
Reach "Mitsurugi" zeal level
Clear Easy difficulty
Clear Normal difficulty
Clear Hard difficulty
Clear Very Hard difficulty
Defeat stage 5 boss "Magatsu Suzuka" (any difficulty)
Defeat stage 6 boss "Magatsu Hino Tsurugi" (any difficulty)
Defeat 1000 enemies
Perform 10 Counters
Perform 10 Flourishes
Clear Inferno difficulty