Here is the full list of all 45 Million Arthur: Arcana Blood achievements.
Complete STORY Mode.
Land 20 hits with a Million Skill (excluding VERSUS, NETWORK Modes).
Battle against Arcana Blood Corrupted Iai Arthur.
Cancel Iai Arthur's Pierce Through without unleashing the attack (excluding VERSUS, NETWORK Modes).
Activate Elemental Boost (excluding VERSUS, NETWORK Modes).
Achieve a perfect victory (excluding VERSUS, NETWORK Modes).
Play the TUTORIAL.
Unleash a Limit Break (excluding VERSUS, NETWORK Modes).
Land a Support Knight attack to perform a combo (excluding VERSUS, NETWORK Modes).
Perform a Million Blade Combo (excluding VERSUS, NETWORK Modes).
Unlock all achievements.
Complete EPISODES OF ARCANA BLOOD.
Customize a Knight (excluding VERSUS, NETWORK Modes).
Summon every single Knight (excluding VERSUS, NETWORK Modes).
Inflict a total of 500,000 damage during TRAINING.
Complete TIME TRIAL Mode.
Set your opponent's Knight Summon Cost to 5 (excluding VERSUS, NETWORK Modes).
Summon Otherworldly Hawkeye with Otherworldly Riesz (excluding VERSUS, NETWORK Modes).
Summon Clone Merchant Arthur and activate Super Armor (excluding VERSUS, NETWORK Modes).
Summon the unmasked Unique Little Grey (excluding VERSUS, NETWORK Modes).
Land 2 or more hits with Foible Elle during a combo (excluding VERSUS, NETWORK Modes).
Summon Otherworldly Akira Oono in TIME TRIAL Mode.
Successfully perform Fortress Breaker with Twinblade Arthur (excluding VERSUS, NETWORK Modes).
Land additional hits with Blade-Protector Arthur's Rising Heaven (excluding VERSUS, NETWORK Modes).
Move using Thief Arthur's Wire Shot (excluding VERSUS, NETWORK Modes).
Unleash Zechs Siegfried's Elemental Cannon (excluding VERSUS, NETWORK Modes).
Perform Freezing Seal with Hybrid Nimue (excluding VERSUS, NETWORK Modes).
Land a hit with Type II Bisclavret's Burning Spiral (excluding VERSUS, NETWORK Modes).
Land a hit with Void Eternal Flame's Magic Turret (excluding VERSUS, NETWORK Modes).
Successfully perform Unique Snow White's Seventh Shoulder Tackle (excluding VERSUS, NETWORK Modes).
Land a hit with Otherworldly Riesz's Dragon Fang Spear (excluding VERSUS, NETWORK Modes).
Land a hit with Otherworldly Koume Sakiyama's Time for Your Shots! to perform a combo (excluding VERSUS, NETWORK Modes).
Load Wildcat Arthur's Magic Charge with Fire, Ice, and Wind (excluding VERSUS, NETWORK Modes).
Successfully link Otherworldly Iori Yagami's in air C to 108 Shiki・Yamibarai in a combo (excluding VERSUS, NETWORK Modes).
Land 20 hits with a Million Excalibur (excluding VERSUS, NETWORK Modes).
Finish off an opponent with Million Excalibur 5 or more times (excluding VERSUS, NETWORK Modes).
Play VERSUS Mode.
Achieve 5 victories in VERSUS Mode.
Play 20 matches in VERSUS Mode.
Achieve a Fire Elemental Bonus of at least 2.0 in a single Combo (excluding VERSUS, NETWORK Modes).
Achieve a Ice Elemental Bonus of at least 2.0 in a single Combo (excluding VERSUS, NETWORK Modes).
Achieve a Wind Elemental Bonus of at least 2.0 in a single Combo (excluding VERSUS, NETWORK Modes).
Battle against Twinblade Arthur using Iai Arthur (excluding VERSUS, NETWORK Modes).
Use Elemental Counter to land Fire, Ice, and Wind Elemental hits during a single Combo (excluding VERSUS, NETWORK Modes).
Land 20 hits on your opponent with a Limit Break (excluding VERSUS, NETWORK Modes).