Here is the full list of all 12 Mighty Gunvolt achievements.
Defeat a boss without taking damage
Clear all 9 stages with any character
Obtain 9 lives
View Gunvolt's ending
Reach a boss without defeating any enemies
View Ekoro's ending
Befriend 10 enemies in one stage with Ekoro
View Beck's ending
Discover the hidden butterfly
Obtain more than 30,000 points in a single stage
Defeat a boss
Get a x1.50 combo