Here is the full list of all 50 Marvel's Avengers achievements. It takes around 100-120 hours to unlock all of the achievements on Windows.
Complete 50 Hive missions
Open 50 Caches strongboxes
Earn a total of 250 Hero Levels across the entire Hero Roster
Rescue 100 AIM prisoners
Complete 30 War Zones at Challenge III or higher rating
Complete HARM Challenges I to V
Complete 15 Villain Sectors
Complete an Elite Heroic Hive
Complete 100 assignments
Complete the "Iconic Avengers" mission chain
Complete five Hive missions
Equip all Legendary or better gear with any hero
Collect 50 intelligence files
Earn a 100% rating for any War Zone at Challenge IV rating
Reach Power Level 150 with any Hero
Fully upgrade a major artifact
Fully upgrade any gear item
Reach Hero Level 50 and purchase all skills for any Hero
Purchase an item from two different faction vendors
Complete the "A Global Offensive" mission chain
Break into 30 Depots
Collect 500 gear items
Complete any mission in under three minutes
Defeat MODOK and the Kree
Reach Hero Level 5 with five different Heroes
Reunite the Avengers
Complete 10 assignments
Rescue Captain America
Reach the AIM space station
Open 100 strongboxes
Stop the Helicarrier from crashing into New York City
Rescue Inhumans from the research facility
Recruit Black Widow
Reach rank 25 in any faction
Reach a combo of 20 hits or higher
Locate the Ant Hill
Earn a 100% rating on a mission without any team member being downed
Destroy the AIM arc reactor
Recruit Tony Stark
Defeat any 20 different enemy types
Recover the SHIELD Protocols
Earn a five star rating on an objective without any team member taking damage
Collect three Artifacts
Recruit Bruce Banner
Defeat 50 enemies with Assault Heroic or Ultimate Heroic abilities
Discover the location of the Chimera
Escape the clutches of AIM in New Jersey
Defeat 10 or more enemies with a single Heroic ability activation
Reach the VIP balcony
Collect a full comic set