Full list of all 25 Magic: The Gathering - Duels of the Planeswalkers 2013 achievements.
The base game contains 20 achievements, and there is 1 DLC pack containing 5 achievements.
Win a campaign duel with an opponent's library empty
Win a duel controlling at least ten creatures
Win a duel controlling a creature with at least 10 power
Cast a mythic rare card
Win a campaign duel with 20 or more life
Win a duel when an opponent controls no creatures
Solve a challenge
Defeat an encounter
Defeat Talrand in the campaign
Enter the deck manager
Win a 3-player, 4-player, or Two-Headed Giant duel
Win a Two-Headed Giant duel
Win a Planechase campaign duel
Win a duel online
Unlock a card for each of ten different decks
Unlock 30 cards for one deck
Solve the Say Your Praetors challenge in all five ways
Defeat Nicol Bolas in the revenge campaign
Defeat ten encounters
Solve ten challenges
Defeat the Sepulchral Strength deck in the revenge campaign
Win a duel controlling at least five Auras
Win a duel controlling at least twenty creatures
Win a duel with exactly 1 life
Win a duel online using an expansion deck