Full list of all 25 Magic: The Gathering - Duels of the Planeswalkers 2013 achievements.
The base game contains 20 achievements, and there is 1 DLC pack containing 5 achievements.
Solve ten challenges
Solve the Say Your Praetors challenge in all five ways
Unlock a card for each of ten different decks
Win a duel controlling at least ten creatures
Defeat ten encounters
Win a Planechase campaign duel
Cast a mythic rare card
Defeat Nicol Bolas in the revenge campaign
Unlock 30 cards for one deck
Win a 3-player, 4-player, or Two-Headed Giant duel
Win a Two-Headed Giant duel
Solve a challenge
Win a campaign duel with an opponent's library empty
Win a duel controlling a creature with at least 10 power
Win a duel online
Win a campaign duel with 20 or more life
Defeat an encounter
Defeat Talrand in the campaign
Win a duel when an opponent controls no creatures
Enter the deck manager
Defeat the Sepulchral Strength deck in the revenge campaign
Win a duel controlling at least five Auras
Win a duel controlling at least twenty creatures
Win a duel with exactly 1 life
Win a duel online using an expansion deck