Here is the full list of all 17 Madballs in Babo:Invasion achievements.
Win an 8+ player Invasion game
Win a 6+ player CTF game with the most points on your team
Find all 50 secrets in the campaign
25 kills using the Striker energy mode
Achieve the top Hero Rank
Unlock the Hero Ranks
Host a 4-Player co-op game
Win 5 games of Team Skirmish
Play with somebody who has the Playbrains rules achievement
Get over 2500 points in a skirmish match
Unlock the Officer Ranks
Crush 100 enemies using Magmor's Colossus ability
Play as every Scorched class in a versus match
A fierce kill using every weapon
Play as every B*D*I class in a versus match
Finish the campaign
Unlock your first item