Here is the full list of all 15 METAL SLUG achievements. It takes around 6-8 hours to unlock all of the achievements on Windows.
Clear the game using no continue
Free 100 POWs
Kill 1,000 enemy soldiers
Throw 200 grenades
Defeat a boss using the METAL SLUG ATTACK
Free 50 POWs
Play in MULTIPLAYER
Clear FINAL MISSION
Clear MISSION 5
Clear MISSION 4
Throw 50 grenades
Kill 200 enemy soldiers
Clear MISSION 3
Clear MISSION 2
Clear MISSION 1