Here is the full list of all 18 METAL GEAR SOLID - there are Master Collection Version achievements.
Complete all VR training missions
Obtain the stealth camo
Exorcise a ghost photo
Complete a VR training mission
Obtain the bandana
Obtain the Fox or Big Boss codename
Defeat Liquid Snake
Defeat Metal Gear REX
Defeat Vulcan Raven
Defeat Hind D
Prevail in the rematch against Sniper Wolf
Defeat Sniper Wolf
Defeat Psycho Mantis
Defeat Ninja
Defeat the M1 Tank
Defeat Revolver Ocelot
Read all the pages in the Screenplay Book
Begin a new game