Here is the full list of all 18 METAL GEAR SOLID - there are Master Collection Version achievements.
Exorcise a ghost photo
Complete all VR training missions
Obtain the bandana
Obtain the Fox or Big Boss codename
Read all the pages in the Screenplay Book
Obtain the stealth camo
Complete a VR training mission
Defeat Liquid Snake
Defeat Metal Gear REX
Defeat Vulcan Raven
Prevail in the rematch against Sniper Wolf
Defeat Hind D
Defeat Sniper Wolf
Defeat Psycho Mantis
Defeat Ninja
Defeat the M1 Tank
Defeat Revolver Ocelot
Begin a new game