Here is the full list of all 60 Metal Gear Rising: Revengeance achievements. It takes around 60-80 hours to unlock all of the achievements on Windows.
Successfully complete 50 Executions during story mode.
Cut off Metal Gear RAY's metal tail during File R-00.
Complete File R-07: Assassination Attempt.
Complete File R-06: Badlands Showdown.
Complete File R-05: Escape From Denver.
Complete File R-04: Hostile Takeover.
Cut off the finial at the top of the pagoda in File R-04.
Destroy a total of 10 Fenrirs during story mode.
Complete File R-03: Mile High.
In story mode, successfully parry 10 attacks in a row in one minute or less.
Dismember three enemies during Blade Mode with a single attack.
Complete the abandoned railroad sequence in File R-03 without using AR Mode.
Destroy a total of 10 Sliders during story mode.
Complete File R-02: Research Facility.
While remotely operating a Dwarf Gekko in story mode, find and communicate with all Dwarf Gekkos.
Incapacitate all the soldiers in File R-02 using a Dwarf Gekko.
Destroy a total of 10 Raptors during story mode.
Destroy a total of 10 Mastiffs during story mode.
Complete File R-01: Coup d'État.
Destroy a total of 30 Dwarf Gekkos during story mode.
Destroy a total of 10 Hammerheads during story mode.
Successfully complete 30 Ninja Kills during story mode.
Destroy a total of 10 Gekkos during story mode.
Successfully complete 50 Zandatsus during story mode.
Complete File R-00: Guard Duty.
In story mode, kill 100 enemies by cutting them.
Destroy a total of 100 Cyborgs during story mode.
Complete story mode on Revengeance difficulty with all S rankings.
Destroy all the Gun Cameras in File R-01.
Complete File R-05 in less than 7 minutes.
Arrive at the objective in File R-07 without being spotted.
Defeat Mistral without taking any damage on Hard difficulty or above.
Defeat Monsoon without taking any damage on Hard difficulty or above.
Defeat Sundowner without taking any damage on Hard difficulty or above.
Defeat Samuel without taking any damage on Hard difficulty or above.
Defeat Sen. Armstrong without taking any damage on Hard difficulty or above.
Destroy a total of 100 Custom Cyborgs during story mode.
Destroy a total of 100 Heavily Armed Cyborgs during story mode.
Destroy a total of 5 Vodomjerka during story mode.
Destroy all of the humanoid Dwarf Gekkos during story mode.
Successfully complete 10 No Kill battles during story mode.
Acquire all customization items.
Acquire all enemy officers' left arms.
Listen to most of the codec conversations.
Discover all of the soldiers hidden in cardboard boxes.
Acquire all data storage devices.
Rescue all the civilians.
Unlock every VR Mission.
Complete every VR Mission.
Set the highest score on every VR Mission.
Complete every DL-VR Mission.
Set the highest score on every DL-VR Mission.
Complete DL-Story-01: Brazilian Wind
Complete DL-Story-01: Brazilian Wind on Revengeance difficulty in one hour or less.
Defeat 100 enemies in DL-Story-01: Brazilian Wind's Story Mode using Quick Draw.
Complete DL-Story-02: Blade Wolf.
Defeat Khamsin without taking any damage on Hard difficulty or above.
Complete DL-Story-02: Blade Wolf on Revengeance difficulty in one hour or less.
Defeat 30 enemies in DL-Story-02: Blade Wolf via Hunt Kills.