Here is the full list of all 25 Little Witch Academia: Chamber of Time achievements.
Watch the Diana Episode.
Collect all of the room decorations.
Watch the Sucy Episode.
Learn all of the battle spells.
Earn the title of Laundry King in the Laundry King Championship.
Obtain the journalism club microphone.
Collect all volumes of Night Fall.
Watch the Jasminka Episode.
Watch the Akko Episode.
Become the Queen of Spice in the Super-Spicy Showdown.
Watch the Constanze Episode.
Watch the Amanda Episode.
Watch the Lotte Episode.
Complete the Ghost Witch and Last Nightmare.
Recover 18 Chariot Cards.
Obtain the Shooting Star Replica.
Complete the Time Demon and the Labyrinth.
Obtain the Pollux Key and traverse the Labyrinth of Pollux.
Complete the Hourglass of Fire and Ice.
Obtain the Gienah Key and traverse the Gienah Tundra.
Obtain the Shaula Key and traverse the Shaula Desert.
Obtain the Regulus Key and traverse the Regulus Mines.
Complete the Guard Dog and the Pendulum.
Obtain the Ankaa Key and traverse Mt. Ankaa.
Obtain the Mimosa Key and traverse the Mimosa Forest.