Here is the full list of all 39 LEGO The Hobbit achievements. It takes around 35-40 hours to unlock all of the achievements on Windows.
Achieve 100% completion
Collect all characters. (Single Player Only)
Complete all the quests in Middle-earth. (Single Player Only)
Forge all the Mithril Treasure Items. (Single Player Only)
Forge all the Perfect Mithril Treasure Items. (Single Player Only)
Collect 10,000,000,000 studs. (Single Player Only)
Collect all Mithril Bricks. (Single Player Only)
Use every Dwarf from Thorin's Company in a Buddy-Up attack
Collect all Treasure Items in levels. (Single Player Only)
Collect all Minikits. (Single Player Only)
Obtain all Master Burglar titles. (Single Player Only)
Collect all Schematics. (Single Player Only)
Equip yourself with Dazzle Wig, Mithril Rhythm Stick and Mithril Dance Boots.
Use Gandalf's startle ability to dazzle 50 enemies
Use 50 Buddy-Up attacks
Transform to Beorn's bear form.
Create a custom character.
Complete the Bonus Level
Complete ''Inside Information''
Complete ''On the Doorstep''
Obtain 150,000 studs from Instruction Builds bonuses. (Single Player Only)
Complete ''The Necromancer''
Complete ''Looking for Proof''
Complete ''A Warm Welcome''
Complete ''Barrels Out of Bond''
Complete ''Flies and Spiders''
Complete ''Queer Lodgings''
Complete ''Out of the Frying Pan…''
Complete ''Goblin Town''
Complete ''Over Hill and Under Hill''
Complete ''The Troll Hoard''
Complete the mining game perfectly 50 times
Equip Thorin with the Mithril Mushroom Crown
Complete ''Roast Mutton''
Complete ''Azog the Defiler''
Play a level in co-op
Complete ''An Unexpected Party''
Complete ''Greatest Kingdom in Middle-earth''
Collect 99 of any loot