Full list of all 75 LEGO DC Super-Villains achievements. It takes around 35-40 hours to unlock all of the achievements in the base game on Windows.
The base game contains 45 achievements, and there are 4 DLC packs containing 30 achievements.
Complete ''Mask of the Phantasm''
Complete ''Mask of the Phantasm'' with all Minikits Unlocked
Complete ''Mask of the Phantasm'' after achieving True Villain status
Set both Free Play characters as The Joker and The Joker Animated Series
Complete the Pachinko machine in one go
Complete ''Sivana Escape''
Complete ''Sivana Escape'' with all Minikits Unlocked
Complete ''Sivana Escape'' after achieving True Villain status
Play the ''Sivana Escape'' level as Pride and Gluttony
Transform into Shazam (Movie) in Free Play
Complete ''Sivana Showdown''
Complete ''Sivana Showdown'' with all Minikits Unlocked
Complete ''Sivana Showdown'' after achieving True Villain status
Fight Doctor Sivana with Shazam (Wizard) in Free Play during ''Sivana Showdown''
Ride a Pig as Superman in ''Sivana Showdown''
Complete ''The Summit''
Complete ''The Summit'' with all Minikits Unlocked
Complete ''The Summit'' after achieving True Villain status
Transform from Tigress to Artemis in Free Play
Defeat 10 Ninjas as Aqualad (Young Justice)
Complete ''Ring of Fire''
Complete ''Ring of Fire'' with all Minikits Unlocked
Complete ''Ring of Fire'' after achieving True Villain status
Set both Free Play characters as Aquaman and Aquaman (Gladiator)
In Free Play, sit on the throne as Orm in ''Ring of Fire''
Complete ''The Final Battle''
Complete ''The Final Battle'' with all Minikits Unlocked
Complete ''The Final Battle'' after achieving True Villain status
Fight Orm with King Shark in Free Play during ''The Final Battle''
Defeat 10 Trench enemies as Mera