Here is the full list of all 13 Half-Life 2: Episode One achievements. It takes around 3-4 hours to unlock all of the achievements on Windows.
Escape City 17 with Alyx.
Kill five enemies with the same energy ball.
Destroy the gunship in the hospital attic.
Make it to the bottom of the Citadel's main elevator shaft in one piece.
Survive long enough to get on the parking garage elevator.
Kill an Elite Soldier with his own energy ball.
Help Alyx snipe 30 enemies in Episode One.
Use the cars to squash 15 antlions in Episode One.
Contain the Citadel core.
Contain the Citadel core without killing any stalkers.
Don't let any citizens die when escorting them to the escape train.
Finish the game firing exactly one bullet. Grenade, crowbar, rocket, and Gravity Gun kills are okay!
Use flares to light 15 zombies on fire.