Here is the full list of all 42 Gunpoint achievements. It takes around 6-8 hours to unlock all of the achievements on Windows.
Free an innocent man at the expense of catching a guilty one.
Steal Gessler's technology for Rooke.
Voluntarily tell Katie the truth.
Chicken out of telling Katie the truth at the last minute.
Jump into an Enforcer to knock him through a window.
Notice the story doesn't necessarily gel with the mechanics. Become qualified games journalist.
Knock Fritz Gessler out of his office window.
Slam Fritz Gessler's office door into him.
Shoot Fritz Gessler.
Intimidate Fritz Gessler into surrendering.
Beat Fritz Gessler to death.
Knock Fritz Gessler out with a punch.
Defeat Gessler by rewiring his gun.
Use the Prankspasm to knock out someone who isn't standing near a power socket (outside of the test lab).
Mock the chief of police at a critical moment.
Create a custom mission with at least one objective.
Use the Longshot to make a guard unintentionally shoot another (outside of the test lab).
Complete a mission faster than I can.
Upgrade your battery capacity to the non-figurative max.
Publish your personalised epilogue.
Complete the game.
Kick Fritz Gessler's office door into him.
Catch a guilty man at the expense of freeing an innocent one.
Use the Gatecrashers to kick a door through a window.
Help justify my early, not entirely wise choice of game name by holding someone at gunpoint with the Resolver.
Use the Gatecrashers to kick a door into a guard.
Use the Gatecrashers to kick a door off its hinges.
Tell Gessler that Rooke's hired you to betray him.
Upgrade your Bullfrog Hypertrousers to pounce instantly.
Complete the police chief's missions without incriminating yourself.
Conceal your presence at the DataSec break-in from Mayfield.
Upgrade your Bullfrog Hypertrousers to maximum jump strength.
Use the Hushcracker to jump through a window silently (outside of the test lab).
Wire an elevator button to trigger something when the elevator arrives.
Get knocked down by an opening door.
Use no violence at all on a mission that has guards.
Complete a mission that has guards with no violence, witnesses or loud noises.
Use the Crosslink to create an infinite loop that burns itself out.
Use the Dropshot to land silently from a great height.
Knock a guard out by opening a door into him.
Leave no living witnesses to your presence on a mission that has guards.
This is an achievement in name only. No-one admires you for punching a guy that many times.