Here is the full list of all 42 Gunpoint achievements. It takes around 6-8 hours to unlock all of the achievements on Windows.
Catch a guilty man at the expense of freeing an innocent one.
Mock the chief of police at a critical moment.
Voluntarily tell Katie the truth.
Chicken out of telling Katie the truth at the last minute.
Slam Fritz Gessler's office door into him.
Knock Fritz Gessler out of his office window.
Defeat Gessler by rewiring his gun.
Beat Fritz Gessler to death.
Intimidate Fritz Gessler into surrendering.
Kick Fritz Gessler's office door into him.
Tell Gessler that Rooke's hired you to betray him.
This is an achievement in name only. No-one admires you for punching a guy that many times.
Jump into an Enforcer to knock him through a window.
Notice the story doesn't necessarily gel with the mechanics. Become qualified games journalist.
Complete a mission faster than I can.
Create a custom mission with at least one objective.
Use the Prankspasm to knock out someone who isn't standing near a power socket (outside of the test lab).
Upgrade your battery capacity to the non-figurative max.
Publish your personalised epilogue.
Complete the game.
Knock Fritz Gessler out with a punch.
Shoot Fritz Gessler.
Help justify my early, not entirely wise choice of game name by holding someone at gunpoint with the Resolver.
Use the Gatecrashers to kick a door through a window.
Use the Longshot to make a guard unintentionally shoot another (outside of the test lab).
Use the Gatecrashers to kick a door into a guard.
Use the Gatecrashers to kick a door off its hinges.
Free an innocent man at the expense of catching a guilty one.
Use the Hushcracker to jump through a window silently (outside of the test lab).
Complete the police chief's missions without incriminating yourself.
Steal Gessler's technology for Rooke.
Conceal your presence at the DataSec break-in from Mayfield.
Complete a mission that has guards with no violence, witnesses or loud noises.
Use no violence at all on a mission that has guards.
Knock a guard out by opening a door into him.
Use the Dropshot to land silently from a great height.
Get knocked down by an opening door.
Upgrade your Bullfrog Hypertrousers to pounce instantly.
Upgrade your Bullfrog Hypertrousers to maximum jump strength.
Use the Crosslink to create an infinite loop that burns itself out.
Leave no living witnesses to your presence on a mission that has guards.
Wire an elevator button to trigger something when the elevator arrives.