Here is the full list of all 42 Gunpoint achievements. It takes around 6-8 hours to unlock all of the achievements on Windows.
Catch a guilty man at the expense of freeing an innocent one.
Steal Gessler's technology for Rooke.
Chicken out of telling Katie the truth at the last minute.
Voluntarily tell Katie the truth.
Slam Fritz Gessler's office door into him.
Knock Fritz Gessler out of his office window.
Intimidate Fritz Gessler into surrendering.
Knock Fritz Gessler out with a punch.
Beat Fritz Gessler to death.
Defeat Gessler by rewiring his gun.
Kick Fritz Gessler's office door into him.
Complete the police chief's missions without incriminating yourself.
Create a custom mission with at least one objective.
Use the Prankspasm to knock out someone who isn't standing near a power socket (outside of the test lab).
Publish your personalised epilogue.
Notice the story doesn't necessarily gel with the mechanics. Become qualified games journalist.
Complete the game.
Shoot Fritz Gessler.
Use the Longshot to make a guard unintentionally shoot another (outside of the test lab).
Use the Gatecrashers to kick a door through a window.
Use the Gatecrashers to kick a door off its hinges.
Use the Gatecrashers to kick a door into a guard.
Upgrade your Bullfrog Hypertrousers to pounce instantly.
Upgrade your battery capacity to the non-figurative max.
Free an innocent man at the expense of catching a guilty one.
Knock a guard out by opening a door into him.
Tell Gessler that Rooke's hired you to betray him.
Upgrade your Bullfrog Hypertrousers to maximum jump strength.
Jump into an Enforcer to knock him through a window.
Mock the chief of police at a critical moment.
Help justify my early, not entirely wise choice of game name by holding someone at gunpoint with the Resolver.
Use the Hushcracker to jump through a window silently (outside of the test lab).
Complete a mission faster than I can.
Conceal your presence at the DataSec break-in from Mayfield.
Use no violence at all on a mission that has guards.
Complete a mission that has guards with no violence, witnesses or loud noises.
Get knocked down by an opening door.
Use the Dropshot to land silently from a great height.
Use the Crosslink to create an infinite loop that burns itself out.
Wire an elevator button to trigger something when the elevator arrives.
This is an achievement in name only. No-one admires you for punching a guy that many times.
Leave no living witnesses to your presence on a mission that has guards.