Here is the full list of all 50 Fallout 4 VR achievements.
Complete 50 Misc. Objectives
Collect 20 Vault-Tec Bobbleheads
Kill 5 Giant Creatures
Reach Level 50
Hack 50 Terminals
Get a Homerun
Reach Maximum Relationship Level with a Companion
Complete "The Nuclear Option"
Complete "Ad Victoriam"
Craft 100 Items
Complete "Blind Betrayal"
Reach Maximum Happiness in a Large Settlement
Collect 10 Vault-Tec Bobbleheads
Complete 10 Side Quests
Complete "Nuclear Family"
Decide the Fate of the Commonwealth
Complete "Rockets' Red Glare"
Complete "Underground Undercover"
Complete "Powering Up"
Complete "Mankind-Redefined"
Read 20 Magazines
Create 50 Weapon Mods
Kill 300 People
Placed A Grenade Or Mine While Pickpocketing
Recruit 5 Separate Companions
Complete "Institutionalized"
Complete "The Molecular Level"
Complete "Hunter/Hunted"
Discover 100 Locations
Join the Railroad
Kill 300 Creatures
Complete "Dangerous Minds"
Pick 50 Locks
Reach Level 25
Complete "Reunions"
Complete "Unlikely Valentine"
Gather 1000 Resources Used For Crafting
Complete "Old Guns"
Get a Touchdown
Join the Brotherhood of Steel
Ally with 3 Settlements
Play a Holotape Game
Complete "Sanctuary"
Complete "Taking Independence"
Reach Level 10
Build 100 Workshop Items
Join the Minutemen
Reach Level 5
Complete "When Freedom Calls"
Enter The Wasteland