Here is the full list of all 60 Expeditions: Conquistador achievements.
Attack and destroy a native settlement on Hispaniola
Experience a mutiny
Make camp without giving any of your followers food
Promote a follower to Lieutenant
Complete the game in Iron Man mode on any difficulty
Return to Spain without losing any expedition members
Rebuild Fortaleza De Gutiérrez
Recruit Anacaona for your expedition
Achieve a Flawless Victory in an Escape battle
Kill an enemy with an Interrupt attack
Discover Tenochtitlan
Enter combat with at least 25 points of Equipment assigned to a single unit
Cast off for the mainland!
Save Governor Bernardo De Manzanedo
Complete 5 side quests in Hispaniola
Score a hit with a ranged attack with a 5% hit chance
Nurse a Fatally Injured expedition member back to full health
Revive an incapacitated unit and keep that unit alive until the end of the battle
Kick an enemy into a burning or trapped space
Win all three battles in the Tournament
Complete The Gloaming
Defeat Esteban Gallego
Kill an enemy with a flanking strike
Have all your followers be disabled at the same time
Lose the first tutorial battle
Start the game with only women, as a female character
Resolve the Jungle Drums goal without bloodshed
Recruit Isabela de Yruenes for your expedition
Find all cairns on Hispaniola and compile all the maps of the island
Find all the cairns and compile all the maps of Mexico
Kick off the battle for Tenochtitlan
Kill Moctezuma Xocoyotzin
Save Moctezuma Xocoyotzin
Turn against your allies in their hour of triumph
Marry a native
Form a romantic relationship
Restore Fortaleza De Gutiérrez to its full glory
Aid the escaped slaves
Discover El Dorado
Discover the Fountain Of Youth
Discover the Masaya Volcano tunnels
Inadvertently unleash smallpox on the population of Tenochtitlan
Capture Xochiyohua
Complete The Temple of Death
Achieve fifteen Flawless Victories in a row on Normal or greater difficulty
Win a non-tutorial battle without ever getting within melee distance of an enemy
Win a non-tutorial battle with only Scholars and Doctors
Hit one of your own units with AoE damage
Deal more than 100 points of damage with a single attack
Enter combat with six units at Veteran or higher rank
Kill an enemy unit with a cannon blast
Complete the game on Normal difficulty
Complete the game on Hard difficulty
Complete the game on Insane difficulty
Return to Spain with 50,000 Valuables or more
Unlock all the Codex entries
Fully research all the possible inventions and construct one item of every possible recipe
Recruit all 6 native followers in Mexico in a single playthrough
Sacrifice a member of your expedition
Trade at every market in both campaigns in a single playthrough