Here is the full list of all 97 Divinity: Original Sin 2 achievements. It takes around 200 hours to unlock all of the achievements on Windows.
Complete the game in Tactician Mode
Complete the game in Honour Mode
Lohse: Banish your demon
Beast: Ally with the Queen
Beast: Assassinate the Queen
Discover the hidden entrance to the Academy
Correctly answer all of Crispin's questions
Set Gareth on a path of reconciliation
Kill an enemy using Teleportation
Ascend to Divinity
Complete the game in Explorer Mode
Complete the game in Classic Mode
Purge Rivellon of all Source
Defeated the Kraken
Ifan: Kill Lucian
Craft a scroll
Obtain Anathema
Gain entrance to Lucian's Crypt without following the Path of Blood
Persuade Toyseller Sanders to give you his amulet
Discover Reimond's Lair
The Red Prince: Become the father of dragons
Defeat Adramahlihk
Escape the kraken's clutches
Rescue Arhu
Arrive at Arx
Enter The Arena of the One
Enter the Academy
Convince all party members to let you ascend
Sebille: Serve the Mother Tree
Sebille: Kill the Master
Speak to an animal's spirit
Arrive at the Nameless Isle
Awaken the corrupted Ancestor Tree on Bloodmoon Island
Learn of the Council of Seven's location from The Advocate
Help free Mari from the Voidwoken
Escort Saheila outside without fighting the Lone Wolves
Learn of the Council of Seven's location from a higher power
Unlock your third Source Point slot
Serve Garvan the tainted stew
Become champion of the Driftwood Arena
Unlock your second Source Point slot
Kill Andras, the necromantic dog
Adopt Peeper
Receive Dorotya's kiss
Meet Meistr Siva
Arrive at Reaper's Coast
Enter the Hall of Echoes
Escape Dallis' siege on the Lady Vengeance without killing every minion
Take command of the Lady Vengeance
Equip runes to all of an item's available slots
Welcome Tarquin to the Seekers' service
Defeat Alexandar in Fort Joy
Craft a skill
Face a higher power
Kill Radeka
Rescue Gareth from Braccus' Armoury
Arrive at the Sanctuary of Amadia
Escort the Black Cat out of Fort Joy
Flee Fort Joy for good
Use your first Source Skill
Get caught breaking the law
Remove your Source Collar
Become champion of the Fort Joy arena
Gain the Hero tag
Win a persuasion event
Arrive at Reaper's Eye
Perform a successful theft
Force Dallis to retreat from combat in Fort Joy
Kill Slane
Escape Dallis' siege on the Lady Vengeance after killing every minion
Set Gareth on a path of vengeance
Learn of the Council of Seven's location from Malady
Lockpick your way into Mordus' hidden lair
Take the ferry to Bloodmoon Island
Tame Featherfall
Perform successful surgery on Natalie
Destroy every Voidwoken egg in Reaper's Cove
Pray at every altar on the Nameless Isle
Convince Alexandar to ally with you
Swear to the Covenant
Successfully walk the Path of Blood
Share Source with all of Rivellon
Submit to the God King
Share Divinity with The Doctor
The Red Prince: Kill the Red Princess
Lohse: Embrace your demon
Sebille: Destroy the Mother Tree
Fane: Return the Eternals to Rivellon
Fane: Embrace this strange new world
Ifan: Forgive Lucian
Make a deal with Adramahlihk
Shapeshift into every race
Use the Curse skill
Gain the Villain tag
Craft a grenade
Successfully begin a match in Arena Mode
Successfully begin a Game Master session