Here is the full list of all 97 Divinity: Original Sin 2 achievements. It takes around 200 hours to unlock all of the achievements on Windows.
Complete the game in Explorer Mode
Complete the game in Classic Mode
Complete the game in Tactician Mode
Purge Rivellon of all Source
Share Source with all of Rivellon
Fane: Embrace this strange new world
Fane: Return the Eternals to Rivellon
Ascend to Divinity
Submit to the God King
Defeated the Kraken
Gain entrance to Lucian's Crypt without following the Path of Blood
Obtain Anathema
Lohse: Banish your demon
Defeat Adramahlihk
Rescue Arhu
Gain the Villain tag
The Red Prince: Become the father of dragons
Persuade Toyseller Sanders to give you his amulet
Discover Reimond's Lair
Arrive at Arx
Convince Alexandar to ally with you
Sebille: Kill the Master
Enter The Arena of the One
Enter the Academy
Discover the hidden entrance to the Academy
Arrive at the Nameless Isle
Serve Garvan the tainted stew
Use the Curse skill
Escort Saheila outside without fighting the Lone Wolves
Awaken the corrupted Ancestor Tree on Bloodmoon Island
Learn of the Council of Seven's location from The Advocate
Perform successful surgery on Natalie
Learn of the Council of Seven's location from a higher power
Unlock your third Source Point slot
Help free Mari from the Voidwoken
Become champion of the Driftwood Arena
Unlock your second Source Point slot
Kill Andras, the necromantic dog
Correctly answer all of Crispin's questions
Perform a successful theft
Get caught breaking the law
Receive Dorotya's kiss
Speak to an animal's spirit
Adopt Peeper
Meet Meistr Siva
Arrive at Reaper's Coast
Craft a skill
Enter the Hall of Echoes
Escape Dallis' siege on the Lady Vengeance without killing every minion
Take command of the Lady Vengeance
Welcome Tarquin to the Seekers' service
Defeat Alexandar in Fort Joy
Kill Radeka
Escort the Black Cat out of Fort Joy
Face a higher power
Become champion of the Fort Joy arena
Craft a grenade
Remove your Source Collar
Rescue Gareth from Braccus' Armoury
Arrive at the Sanctuary of Amadia
Equip runes to all of an item's available slots
Craft a scroll
Flee Fort Joy for good
Use your first Source Skill
Kill an enemy using Teleportation
Win a persuasion event
Gain the Hero tag
Arrive at Reaper's Eye
Escape the kraken's clutches
Force Dallis to retreat from combat in Fort Joy
Kill Slane
Escape Dallis' siege on the Lady Vengeance after killing every minion
Set Gareth on a path of vengeance
Set Gareth on a path of reconciliation
Learn of the Council of Seven's location from Malady
Lockpick your way into Mordus' hidden lair
Take the ferry to Bloodmoon Island
Tame Featherfall
Destroy every Voidwoken egg in Reaper's Cove
Pray at every altar on the Nameless Isle
Convince all party members to let you ascend
Swear to the Covenant
Successfully walk the Path of Blood
Share Divinity with The Doctor
The Red Prince: Kill the Red Princess
Lohse: Embrace your demon
Sebille: Serve the Mother Tree
Sebille: Destroy the Mother Tree
Ifan: Kill Lucian
Ifan: Forgive Lucian
Beast: Assassinate the Queen
Make a deal with Adramahlihk
Beast: Ally with the Queen
Shapeshift into every race
Successfully begin a match in Arena Mode
Successfully begin a Game Master session
Complete the game in Honour Mode