Here is the full list of all 25 Diablo IV achievements.
Kill the most challenging Echo of Lilith.
Kill 50 enemies while Berserking as a Barbarian.
Kill 50 enemies in Werebear form and 50 enemies in Werewolf form as a Druid.
Reach Level 50 with a Hardcore character.
Summon 100 Skeleton Mages or Warriors as a Necromancer.
Acquire 10 Caches of Chaos from the Tree of Whispers.
Reach Level 100 with any character.
Upgrade your Healing Potion to max tier.
Craft any Elixir and any Incense.
Imprint 10 items at the Occultist with an Aspect from the Codex of Power.
Upgrade a piece of Armor, Jewelry, and a Weapon.
Collect 1000 Aberrant Cinder in Helltide zones.
Get 5 PvP kills.
Explore all of Estuar.
Complete a Sacred and Ancestral Nightmare Dungeon.
Kill any World Boss.
Kill 50 enemies in melee range and 50 enemies out of melee range as a Rogue.
Complete the campaign.
Reach Level 50 with any character.
Kill 666 Bandits, Cultists, or Knights.
Kill 666 Snakes or Spiders.
Kill 666 Drowned, Vampires, or Werewolves.
Kill 100 enemies with Fire, Frost, or Lightning damage as a Sorcerer.
Kill 666 Ghosts, Skeletons, or Zombies.
Kill 666 Demons, Fallen, or Goatmen.