Here is the full list of all 25 Diablo IV achievements.
Complete a Sacred and Ancestral Nightmare Dungeon.
Kill 100 enemies with Fire, Frost, or Lightning damage as a Sorcerer.
Get 5 PvP kills.
Imprint 10 items at the Occultist with an Aspect from the Codex of Power.
Craft any Elixir and any Incense.
Kill 666 Snakes or Spiders.
Kill 666 Ghosts, Skeletons, or Zombies.
Upgrade a piece of Armor, Jewelry, and a Weapon.
Kill 666 Bandits, Cultists, or Knights.
Kill 666 Demons, Fallen, or Goatmen.
Kill 666 Drowned, Vampires, or Werewolves.
Kill 50 enemies while Berserking as a Barbarian.
Complete the campaign.
Collect 1000 Aberrant Cinder in Helltide zones.
Reach Level 50 with any character.
Reach Level 50 with a Hardcore character.
Upgrade your Healing Potion to max tier.
Kill any World Boss.
Kill 50 enemies in Werebear form and 50 enemies in Werewolf form as a Druid.
Explore all of Estuar.
Reach Level 100 with any character.
Summon 100 Skeleton Mages or Warriors as a Necromancer.
Kill 50 enemies in melee range and 50 enemies out of melee range as a Rogue.
Kill the most challenging Echo of Lilith.
Acquire 10 Caches of Chaos from the Tree of Whispers.