Here is the full list of all 25 Diablo IV achievements.
Kill 50 enemies while Berserking as a Barbarian.
Explore all of Estuar.
Complete a Sacred and Ancestral Nightmare Dungeon.
Collect 1000 Aberrant Cinder in Helltide zones.
Upgrade a piece of Armor, Jewelry, and a Weapon.
Craft any Elixir and any Incense.
Kill any World Boss.
Complete the campaign.
Reach Level 50 with any character.
Kill 666 Snakes or Spiders.
Kill 666 Ghosts, Skeletons, or Zombies.
Kill 666 Drowned, Vampires, or Werewolves.
Kill 666 Bandits, Cultists, or Knights.
Kill 666 Demons, Fallen, or Goatmen.
Kill 100 enemies with Fire, Frost, or Lightning damage as a Sorcerer.
Imprint 10 items at the Occultist with an Aspect from the Codex of Power.
Kill 50 enemies in Werebear form and 50 enemies in Werewolf form as a Druid.
Reach Level 50 with a Hardcore character.
Reach Level 100 with any character.
Summon 100 Skeleton Mages or Warriors as a Necromancer.
Upgrade your Healing Potion to max tier.
Get 5 PvP kills.
Kill 50 enemies in melee range and 50 enemies out of melee range as a Rogue.
Kill the most challenging Echo of Lilith.
Acquire 10 Caches of Chaos from the Tree of Whispers.