Here is the full list of all 54 Deployment achievements.
Lose 125 matches
Win 125 matches
Kill 500 enemies as gunner
Kill 500 enemies as pyro
Lose 100 matches
Kill 300 enemies as pyro
Kill 500 enemies as sniper
Kill 500 enemies as laser
Win 100 matches
Kill 300 enemies as laser
Lose 75 matches
Kill 500 enemies as rocketeer
Win 75 matches
Kill 300 enemies as rocketeer
Kill 100 enemies as rocketeer
Lose 50 matches
Kill 100 enemies as laser
Kill 1000 enemies
Lose 25 matches
Kill 300 enemies as sniper
Win 50 matches
Kill 100 enemies as sniper
Kill 100 enemies as pyro
Finish match, collecting only one boost
Win match without killing anyone
Get your minions kill 50 enemies
Kill invisible enemy
Win 25 matches
Capture 50 minions spawners
Finish match without dying
Make 25 triple kills
Kill 300 enemies as gunner
Spawn 75 minions
Kill 50 minions
Capture 50 turrets
Make 25 double kills
Capture 50 touch heals
Pass through 750 doors
Capture 50 heals
Capture 50 scanners
Collect 150 boosts
Deactivate 100 systems
Pass through 500 doors
Kill enemy, when you have 5% HP or less
Kill 100 enemies as gunner
Do not die in tutorial
Win 3 matches in row
Pass through 250 doors
Win match without capturing systems
Make 25 mega kills
Deal 5000 damage to systems
Survive 200 damage
Deal 9001 damage to enemies
Capture all systems on level