Here is the full list of all 54 Deployment achievements.
Lose 125 matches
Lose 100 matches
Lose 75 matches
Lose 50 matches
Lose 25 matches
Do not die in tutorial
Kill 500 enemies as pyro
Kill 300 enemies as pyro
Kill 500 enemies as laser
Win 125 matches
Kill 300 enemies as laser
Kill 500 enemies as rocketeer
Win 100 matches
Kill 300 enemies as rocketeer
Kill 500 enemies as sniper
Win 75 matches
Kill 300 enemies as sniper
Kill 100 enemies as laser
Kill 1000 enemies
Get your minions kill 50 enemies
Kill 100 enemies as rocketeer
Kill 100 enemies as pyro
Win 50 matches
Capture 50 minions spawners
Kill 50 minions
Kill 500 enemies as gunner
Finish match without dying
Win match without killing anyone
Kill 100 enemies as sniper
Deactivate 100 systems
Win 25 matches
Make 25 triple kills
Kill 300 enemies as gunner
Make 25 double kills
Capture 50 touch heals
Spawn 75 minions
Collect 150 boosts
Capture 50 turrets
Capture 50 heals
Pass through 750 doors
Kill invisible enemy
Finish match, collecting only one boost
Capture 50 scanners
Pass through 500 doors
Win match without capturing systems
Kill 100 enemies as gunner
Pass through 250 doors
Win 3 matches in row
Deal 5000 damage to systems
Make 25 mega kills
Capture all systems on level
Deal 9001 damage to enemies
Kill enemy, when you have 5% HP or less
Survive 200 damage