Here is the full list of all 34 Demonheart achievements.
Finish the game as Good Bright and as Evil Bright.
Kiss Ari.
Finish Chapter 5.
Decipher the whole message in Chapter 5.
Max out both Evil and Defiant points.
Max out both Evil and Tactful points.
Max out both Good and Defiant points.
Kill Mark.
Molest the demonspawn.
Read the book about demonspawn in Chapter 1.
Finish Chapter 4.
Read all the entries of Rivera's journal.
Decipher the message in Chapter 4.
Max out both Good and Tactful points.
Finish Chapter 3.
Ask the demonspawn as many questions as you can.
Decipher all the messages in Chapter 3.
Kiss Sir Brash.
Finish Chapter 2.
Decipher the message in Chapter 2.
Finish Chapter 1.
Decipher all the messages in Chapter 1.
Examine Mr. Edgardo after the dinner with Orchid.