Here is the full list of all 45 Dead or Alive 5 Last Round achievements.
Successfully deliver a Power Launcher.
Successfully land a Power Blow.
See 8 characters' losing poses.
Watch a movie.
Play Free Training mode for 1 hour.
Clear 1 course in Arcade (tag) mode.
Take a photo in Spectator mode.
Play Spectator mode.
View your results in Fight Record.
Clear 1 course in Time Attack (solo) mode.
Played in Combo Challenge.
Change the background music settings.
Successfully attack during a Cliffhanger.
Play a Ranked match.
Set "Throwdowns" to "Accept" and have a Throwdown in Versus, Arcade, or Free Training mode.
Fight online.
Clear 1 course in Survival (solo) mode.
Clear 1 course in Time Attack (tag) mode.
Play in Tutorial.
Fight a Versus (tag) match.
Fight a tag match.
Have a Team Fight.
Clear 1 course in Arcade (solo) mode.
Fight a Versus (solo) match.
Win without taking any damage.
Turn Danger Zones off on the Stage Select screen.
Have your first fight outside of Training or Versus modes.
Display the Move List.
Unlock all achievements.
Fight online 10 times.
Fight online 100 times.
Trigger the Special Danger Zone in The Show.
Trigger the Special Danger Zone in Hot Zone.
Trigger the Special Danger Zone in Sky City Tokyo.
Set "Throwdowns" to "Accept" and have 10 Throwdowns in Versus, Arcade, or Free Training mode.
Clear 1 course in Survival (tag) mode.
Complete all moves for a character in Command Training.
Complete all lessons in Tutorial.
Complete all lessons for a character in Combo Challenge.
Do a character-specific tag throw.
Display the Move Details.
Save a replay.
Do 10 different character-specific tag throws.
Press H+P+K during a Power Blow to tag in a partner and deliver a Tag Power Blow.
Successfully block an opponent's attack during a Cliffhanger.