Here is the full list of all 45 Dead or Alive 5 Last Round achievements.
Play Free Training mode for 1 hour.
Set "Throwdowns" to "Accept" and have 10 Throwdowns in Versus, Arcade, or Free Training mode.
Successfully block an opponent's attack during a Cliffhanger.
Successfully attack during a Cliffhanger.
Fight online 10 times.
Clear 1 course in Time Attack (solo) mode.
Set "Throwdowns" to "Accept" and have a Throwdown in Versus, Arcade, or Free Training mode.
Clear 1 course in Time Attack (tag) mode.
Clear 1 course in Survival (tag) mode.
Clear 1 course in Survival (solo) mode.
Complete all moves for a character in Command Training.
Successfully deliver a Power Launcher.
Press H+P+K during a Power Blow to tag in a partner and deliver a Tag Power Blow.
Played in Combo Challenge.
Do 10 different character-specific tag throws.
Do a character-specific tag throw.
Clear 1 course in Arcade (solo) mode.
Clear 1 course in Arcade (tag) mode.
Win without taking any damage.
Trigger the Special Danger Zone in Sky City Tokyo.
Trigger the Special Danger Zone in The Show.
Trigger the Special Danger Zone in Hot Zone.
Play in Tutorial.
Fight a tag match.
Fight a Versus (tag) match.
Successfully land a Power Blow.
Have a Team Fight.
Fight a Versus (solo) match.
Display the Move Details.
Turn Danger Zones off on the Stage Select screen.
Change the background music settings.
View your results in Fight Record.
Watch a movie.
See 8 characters' losing poses.
Display the Move List.
Take a photo in Spectator mode.
Play Spectator mode.
Save a replay.
Play a Ranked match.
Have your first fight outside of Training or Versus modes.
Fight online.
Unlock all achievements.
Fight online 100 times.
Complete all lessons in Tutorial.
Complete all lessons for a character in Combo Challenge.