Here is the full list of all 45 Dead or Alive 5 Last Round achievements.
Unlock all achievements.
Fight online 100 times.
Complete all lessons in Tutorial.
Complete all lessons for a character in Combo Challenge.
Set "Throwdowns" to "Accept" and have 10 Throwdowns in Versus, Arcade, or Free Training mode.
Fight online 10 times.
Complete all moves for a character in Command Training.
Do 10 different character-specific tag throws.
Successfully block an opponent's attack during a Cliffhanger.
Trigger the Special Danger Zone in Hot Zone.
Press H+P+K during a Power Blow to tag in a partner and deliver a Tag Power Blow.
Trigger the Special Danger Zone in The Show.
Successfully deliver a Power Launcher.
Clear 1 course in Time Attack (tag) mode.
Clear 1 course in Survival (tag) mode.
Clear 1 course in Survival (solo) mode.
Have a Team Fight.
Successfully attack during a Cliffhanger.
Do a character-specific tag throw.
Clear 1 course in Time Attack (solo) mode.
Played in Combo Challenge.
Trigger the Special Danger Zone in Sky City Tokyo.
Clear 1 course in Arcade (tag) mode.
See 8 characters' losing poses.
Successfully land a Power Blow.
Clear 1 course in Arcade (solo) mode.
Play Free Training mode for 1 hour.
Display the Move List.
Set "Throwdowns" to "Accept" and have a Throwdown in Versus, Arcade, or Free Training mode.
Display the Move Details.
Fight online.
Play a Ranked match.
Have your first fight outside of Training or Versus modes.
Play in Tutorial.
View your results in Fight Record.
Fight a Versus (tag) match.
Fight a tag match.
Watch a movie.
Take a photo in Spectator mode.
Play Spectator mode.
Win without taking any damage.
Turn Danger Zones off on the Stage Select screen.
Save a replay.
Fight a Versus (solo) match.
Change the background music settings.