Here is the full list of all 45 Dead or Alive 5 Last Round achievements.
Fight online 10 times.
Set "Throwdowns" to "Accept" and have a Throwdown in Versus, Arcade, or Free Training mode.
Fight a Versus (tag) match.
Fight a tag match.
Played in Combo Challenge.
Clear 1 course in Arcade (solo) mode.
Win without taking any damage.
Play a Ranked match.
Fight online.
Save a replay.
Fight a Versus (solo) match.
Display the Move List.
Display the Move Details.
View your results in Fight Record.
Watch a movie.
Play in Tutorial.
Turn Danger Zones off on the Stage Select screen.
Change the background music settings.
Take a photo in Spectator mode.
Play Spectator mode.
Have your first fight outside of Training or Versus modes.
Unlock all achievements.
Fight online 100 times.
Trigger the Special Danger Zone in The Show.
Trigger the Special Danger Zone in Hot Zone.
Trigger the Special Danger Zone in Sky City Tokyo.
Set "Throwdowns" to "Accept" and have 10 Throwdowns in Versus, Arcade, or Free Training mode.
Clear 1 course in Arcade (tag) mode.
Clear 1 course in Time Attack (solo) mode.
Clear 1 course in Time Attack (tag) mode.
Clear 1 course in Survival (solo) mode.
Clear 1 course in Survival (tag) mode.
Play Free Training mode for 1 hour.
Complete all moves for a character in Command Training.
Complete all lessons in Tutorial.
Complete all lessons for a character in Combo Challenge.
Do a character-specific tag throw.
Have a Team Fight.
Do 10 different character-specific tag throws.
Successfully land a Power Blow.
Successfully deliver a Power Launcher.
Press H+P+K during a Power Blow to tag in a partner and deliver a Tag Power Blow.
Successfully attack during a Cliffhanger.
Successfully block an opponent's attack during a Cliffhanger.
See 8 characters' losing poses.