Here is the full list of all 45 Dead or Alive 5 Last Round achievements.
Clear 1 course in Survival (solo) mode.
Clear 1 course in Arcade (tag) mode.
Clear 1 course in Time Attack (solo) mode.
Play in Tutorial.
Play Spectator mode.
Change the background music settings.
Played in Combo Challenge.
Press H+P+K during a Power Blow to tag in a partner and deliver a Tag Power Blow.
Fight a tag match.
Fight a Versus (tag) match.
Turn Danger Zones off on the Stage Select screen.
View your results in Fight Record.
Clear 1 course in Arcade (solo) mode.
Successfully land a Power Blow.
Win without taking any damage.
Display the Move Details.
Display the Move List.
Have your first fight outside of Training or Versus modes.
Fight a Versus (solo) match.
Unlock all achievements.
Fight online.
Fight online 10 times.
Fight online 100 times.
Play a Ranked match.
Trigger the Special Danger Zone in The Show.
Trigger the Special Danger Zone in Hot Zone.
Trigger the Special Danger Zone in Sky City Tokyo.
Set "Throwdowns" to "Accept" and have a Throwdown in Versus, Arcade, or Free Training mode.
Set "Throwdowns" to "Accept" and have 10 Throwdowns in Versus, Arcade, or Free Training mode.
Clear 1 course in Time Attack (tag) mode.
Clear 1 course in Survival (tag) mode.
Play Free Training mode for 1 hour.
Complete all moves for a character in Command Training.
Complete all lessons in Tutorial.
Complete all lessons for a character in Combo Challenge.
Do a character-specific tag throw.
Take a photo in Spectator mode.
Save a replay.
Watch a movie.
Have a Team Fight.
Do 10 different character-specific tag throws.
Successfully deliver a Power Launcher.
Successfully attack during a Cliffhanger.
Successfully block an opponent's attack during a Cliffhanger.
See 8 characters' losing poses.