Here is the full list of all 33 Cosmic Star Heroine achievements.
Complete the game
Defeat a true hero
Defeat a cosmic entity
Defeat the Prime Evil
Reclaim your high score
Gain at least 20 recruits for your ship
A party member betrays you
Defeat a special bounty
Gain Chahn's ultimate ability
Defeat the ultimate zombie
Deal over 9999 damage in a single hit
Find the ultimate ingredient
Gain your final party member
Prove your innocence
Defeat the Crystal Wraith
Defeat the Nightmare
Escape confinement
Use Clarke's Self-Destruct ability
Chat with your party members
Commandeer your own spaceship
Win a VR Battle
Use a Heroine program
Defeat the Blobmith
Charm an enemy
Reach 300 Style
Win every round of Rock Paper Scissors
Reach Lauren's apartment
Defeat Spectral Dragon
Scare rats away in Gehenna
Win first battle in game on hardest difficulty level
Defeat the lab guardian
Share a soda
Complete SkyBreaker Tower scenario