Full list of all 80 Borderlands Game of the Year Enhanced achievements. It takes around 60-80 hours to unlock all of the achievements on Windows.
Killed Crawmerax the Invincible
Emerged victorious from an arena match
Won a duel against another player
Won a duel without taking damage
Defeated the Rakk Hive, the Vault Boss, Sledge, Krom, or Flynt in a co-op game
Completed a crazy request for Tannis
Completed the larger challenge in the Hell-Burbia coliseum
Completed the larger challenge in The Angelic Ruins coliseum
Completed the larger challenge in The Gully coliseum
Completed each of the larger challenges in all 3 coliseums
Completed the lesser challenge in all 3 coliseums
Killed the Vault Boss
Killed an enemy plumber-style
I bet you never thought you'd be here
Killed the Rakk Hive
Killed Krom
Killed Flynt
Killed the Interplanetary Ninja Assassin Claptrap
Killed Commandant Steele-trap
Killed Dr. Ned-trap
Killed General Knoxx-trap
Paid for a worthless tour of the world's largest bullet
Killed each of the loot midgets
Destroyed a Lancer while in a Racer
Completed all missions in the Rust Commons
Earned $1,000,000
Killed 25 enemies with corrosive weapons
Killed 15 enemies with the Berserker's action skill
Killed an enemy with the Siren's action skill
Discovered The Scrapyard
Discovered Eridian Promontory
Discovered Crimson Lance Enclave
Discovered Krom's Canyon
Discovered Trash Coast
Completed all missions in Secret Armory
Earned level 30
Earned level 40
Earned level 50
Rescued enough Claptraps to earn 42 inventory slots
Completed the "House of the Ned" mission
Completed the "Jakobs Fodder" mission
Killed Ned...sort of
Killed Ned. Again.
Completed the "Braaaaaaaaaaaaains!" mission
Built the New Car: Monster
Rescued Athena
Destroyed Lance Depot
Reached Level 61
Found all 6 Claptrap statues
Found 25 oil cans
Collected 15 Claptrap bobbleheads
Collected 5 3D glasses
Collected 3 panties, 5 fish in a bag, and 15 pizzas
Reached Level 51
Raced around the Ludicrous Speedway in record time
Completed 5 missions in the Rust Commons
Reached proficiency level 10 with any weapon type
Completed all missions in the Arid Badlands
Earned level 20
Equipped a class mod for your character
Killed Sledge
Applied an elemental artifact
Killed 25 enemies with shock weapons
Completed 15 missions in co-op
Discovered Headstone Mine
Mastered the technology of Pandora
Discovered Sledge's Safe House
Rescued a groupmate from death in a co-op game
Killed 5 Rakk in under 10 seconds
Killed 15 enemies with the Soldier's action skill
Play with at least two other players.
Killed 25 enemies by ramming them with any vehicle
Killed 25 enemies with incendiary weapons
Earned level 10
Killed 15 enemies with the Hunter's action skill
Sold 50 guns to a shop
Discovered Skag Gully
Earned level 5
Killed 25 enemies with explosive weapons
Completed 5 missions in the Arid Badlands